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phosphorus trichloride formula

Posted by on Jan 10, 2021 in Uncategorized

Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl3. Phosphorous trichloride is a popular chemical compound that is majorly used in the production of organophosphorus substance for chemical industries. Related Pages. It can be used to make trioctylphosphine oxide (TOPO), used as an extraction agent, although TOPO is usually made via the corresponding phosphine. 1809 137. Phosphoryl chloride can be prepared by the reaction of phosphorus trichloride with oxygenat 20-50 °C (air is ineffective): 2 PCl3 + O2 → 2 O=PCl3 An alternative synthesis involves the reaction of phosphorus pentachloride and phosphorus pentoxide. They are also used to make insecticides such as diazinon. It can as a nucleophile too for many reactions like Lewis acid or more. Phosphorus trichloride (PCl 3) is a toxic and highly reactive reagent, which, on hydrolysis generates phosphorous acid (H 3 PO 3) and hydrochloric acid, exothermically. Figure 1. Deutsch: Strukturformel von Phosphortrichlorid. 7719 -12 -2 231 -749 -3 015 -007 -00 -4 - 4. Name: Phosphorus Trichloride. The chemical formula for the compound is given as the PCl3 and its molecular weight is calculated 137.33 g mol-1 approx. The melting and boiling points for the chemical compound are written as -93.6 ºC and 76.1 ºC and its density is calculated 1.574 g mL-1 approx. Phosphorus trichloride. It is not found in nature, so it is prepared synthetically. Since these compounds are both solids, a convenient way of performing the reaction is to chlorinate a mixture of PCl3 and P4O10, which generates the PCl5 in situ. Categories: Chlorides | Phosphorus compounds | Nonmetal halides. PCl 5 finds use as a chlorinating reagent. It has a trigonal pyramidal geometry and its chemical structure could be given as below. 23 It readily reacts with alcohols, in the presence of base, to produce phosphite triesters. M. C. Forbes, C. A. Roswell, R. N. Maxson. To use all functions of this page, please activate cookies in your browser. This Lewis basicity is exploited in one useful route to organophosphorus compounds: The (RPCl3)+ product can then be decomposed with water to produce an alkylphosphonic dichloride RP(=O)Cl2. Conversion. Licensing . An industrially relevant reaction of PCl3 with amines is phosphonomethylation, which employs formaldehyde: Aminophosphonates are widely used as sequestring and antiscale agents in water treatment. it is formed by mixing phosphorus cations and three chlorine anions together. ›› Phosphorus Trichloride molecular weight. Molar mass of PCl3 = 137.332761 g/mol. The formation of phosphorus pentachloride is prevented by the presence of a small excess of phosphorus.The heat of reaction, ca. As the PCl3 is consumed, the POCl3becomes the reaction solvent. Display Name: Phosphoryl trichloride EC Number: 233-046-7 EC Name: Phosphoryl trichloride CAS Number: 10025-87-3 Molecular formula: Cl3OP IUPAC Name: The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Phosphorus trichloride is a phosphorus halide with formula Cl3P. Phosphorus trichloride is a chemical compound. 1. Index -No. It is the most important of the three phosphorus chlorides. it can be used as an intermediate for some chemical reactions like witting reaction. It is sufficiently inexpensive that it would not be synthesized for laboratory use. Phosphorus trichloride reacts vigorously with water to generate gaseous HCl. Linear Formula PCl 3. It is usually prepared from the yellow or white phosphorus gas chlorine. Formula and structure: The phosphorous trichloride chemical formula is PCl 3 and its molar mass is 137.33 g mol -1. it is soluble in benzene and had an interesting chemical behavior. Phosphorus trichloride is the precursor to organophosphorus compounds that contain one or more (P3+) atoms, most notably phosphites and phosphonates. 6 PCl3 + 6 Cl2 → 6 PCl5 6 PCl5 + P4O1… Phosphorus pentachloride is the chemical compound with the formula PCl 5. PubChem Substance ID 57648656 0 - 100 (1) 101 - 200 (9) 201 - 300 (1) Boiling Point (°C) 0 - 100 (3) 101 - 200 (2) 201 - 300 (2) Melting Point (°C) less than 0 (2) ... phosphorus trichloride. These compounds do not usually contain the chlorine atoms found in PCl3. Phosphorous trichloride is a popular chemical compound that is majorly used in the production of organophosphorus substance for chemical industries. PCl3 is toxic, with a concentration of 600 ppm being lethal in just a few minutes[7]. phosphorus pentachloride (PCl5), thiophosphoryl chloride (PSCl3), or phosphorus oxychloride (POCl3). Of all the phosphorus halides formed, most common are phosphorus pentachloride, PCl 5 and phosphorus trichloride, PCl 3. It is used to convert primary and secondary alcohols into alkyl chlorides, or carboxylic acids into acyl chlorides, although thionyl chloride generally gives better yields than PCl3[8]. Read what you need to know about our industry portal chemeurope.com. The reaction of PCl3 with Grignard reagents and organolithium reagents is a useful method for the preparation of organic phosphines with the formula R3P (sometimes called phosphanes) such as triphenylphosphine, Ph3P. Molecular weight calculation: 30.973761 + 35.453*3 ›› Percent composition by element It is an important industrial chemical, being used for the manufacture of organophosphorus compounds for a wide variety of applications. EC Number 231-749-3. Maths Formulas - Class XII | Class XI | Class X | Class IX | Class VIII | Class VII | Class VI | Class V Algebra | Set Theory | Trigonometry | Geometry | Vectors | Statistics | Mensurations | Probability | Calculus | Integration | Differentiation | Derivatives Hindi Grammar - Sangya | vachan | karak | Sandhi | kriya visheshan | Vachya | Varnmala | Upsarg | Vakya | Kaal | Samas | kriya | Sarvanam | Ling. Hint for Writing the Formula for Phosphorus trichloride Since we have two non-metals, P … Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl3. Phosphorus exhibits oxidation numbers that are unusual for a group 15 element in compounds that contain phosphorus-phosphorus bonds; examples include diphosphorus tetrahydride, H 2 P-PH 2, and tetraphosphorus trisulfide, P 4 S 3, illustrated in Figure 1. It is the most important phosphorus halogen. PCl3 is classified as very toxic and corrosive under EU Directive 67/548/EEC, and the risk phrases R14, R26/28, R35 and R48/20 are obligatory. In compounds, phosphorus usually occurs in oxidation states of 3−, 3+, and 5+. Wikipedia article "Phosphorus_trichloride", The references in this article would be clearer with a different or consistent style of. It has a trigonal pyramidal shape. In the absence of base, however, the reaction affords a dialkyl phosphonate and an alkyl chloride, according to the following stoichiometry: Amines, R2NH, form P(NR2)3, and thiols (RSH) form P(SR)3. World production exceeds one-third of a million tonnes. Convert grams Phosphorus Trichloride to moles or moles Phosphorus Trichloride to grams. Copyright © 2020 Andlearning.org Properties Chemical. Phosphorous trichloride, also known as phosphorus (III) chloride, is a chemical compound mainly used in the production of organophosphorus substance for chemical industry. For the printer protocol, see Printer Command Language. Synonyms & Trade Names Phosphorus chloride [Phosphorus trichloride] CAS No. PCl3 is also used directly as a reagent in organic synthesis. Metal complexes such as Ni(PCl3)4 are known. The phosphorus is considered to be in a 3+ oxidation state and each chlorine is considered to be in a 1- oxidation state. Phosphorus trichloride (formula P Cl 3) is the most important of the three phosphorus chlorides. It has a trigonal pyramidal shape, owing to the lone pairs on the phosphorus. PCl3 is important indirectly as a precursor to PCl5, POCl3 and PSCl3. Your browser does not support JavaScript. The phosphorus in PCl3 is often considered to have the +3 oxidation state and the chlorine atoms are considered to be in the -1 oxidation state. To add the actual compound, you should more phosphorus to the mixture. PCl₃ . Phosphorus trichloride is produced by the reaction of yellow phosphorus and chloride. If an electric discharge is passed through a mixture of PCl3 vapour and hydrogen gas, a rare chloride of phosphorus is formed, diphosphorus tetrachloride (P2Cl4). Most of its reactivity is consistent with this description. Formula Weight. Formula. Formula: PCl3. In a Hoechst continuous process, molten white phosphorus and gaseous chlorine react in previously produced phosphorus trichloride. Phosphorus(V) chloride, also known as phosphorus pentachloride, is a chemical compound.Its chemical formula is PCl 5.It contains phosphorus and chloride ions.The phosphorus is in the +5 oxidation state It is widely used in chemical industries and majorly used for the production of pesticides, gasoline, additives, plastics, textiles, medicinal products etc. Phosphorus trichloride is prepared industrially by the reaction of chlorine with a refluxing solution of white phosphorus in phosphorus trichloride, with continuous removal of PCl3as it is formed. which in turn enjoy many applications in herbicides, insecticides, plasticisers, oil additives, and flame retardants. It has a trigonal pyramidal shape. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. A large number of similar substitution reactions are known, the most important of which is the formation of phosphite esters by reaction with alcohols or phenols. DOT ID & Guide. With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter. For Phosphorus trichloride use the hints and resources below to help write the formula. Phosphorus trichloride is a colorless or faint yellow fuming liquid, which readily hydrolyzes in moist air and water releasing a mist of hydrogen chloride, giving the compound a strong HCl odor. It has a trigonal pyramidal shape, owing to the lone pairs on the phosphorus. It is a molecular compound made up of phosphorus covalently bonded to three chlorine atoms. The chemical formula is PCl 3. Chemical Name: Phosphorus trichloride Formula: PCl3 CAS Number: 7719-12-2 Molecular Weight: 137.3 General & Use: Phosphorus trichloride is used as an initial product for numerous inorganic and organic phosphorus compounds mainly in the production of agrochemicals, flame retardants, plasticizers, additives and detergents. For example, with phenol, triphenyl phosphite is formed: where "Ph" stands for phenyl group, -C6H5. Phosphonates include the herbicide glyphosate. © 1997-2021 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Phosphorus_trichloride.html, Your browser is not current. Phosphorus Trichloride (PCl 3) Phosphorus trichloride is a colourless oily liquid and highly toxic compound. It is a toxic and volatile liquid which reacts violently with water to release HCl gas. FIRST AID MEASURES General advice Consult a physician. 10 times the heat of evaporation, keeps the system at its boiling point, and the phosphorus trichloride distills off. Under controlled conditions PCl3 can be used to prepare PhPCl2 and Ph2PCl. Phosphorus Trichloride PCl3 Molar Mass, Molecular Weight. Phosphorus trichloride (formula PCl3) is the most important of the three phosphorus chlorides. To use all the functions on Chemie.DE please activate JavaScript. P4 + 6 Cl2 → 4 PCl3 Industrial production of phosphorus trichloride is controlled under the Chemical Weapons Convention, where it is listed in schedule 3.In the laboratory it may be more convenient to use the less toxic red phosphorus. It is an important industrial chemical, being used for the manufacture of organophosphorus compounds for a wide variety of applications. Date: 13 April 2019: Source: Own work: Author: Chem Sim 2001: SVG development: The source code of this SVG is valid. Phosphorus trichloride. MDL number MFCD00011438. When we look at the physical properties, this is a colorless, yellow liquid with a pungent smell. Find out more about the company LUMITOS and our team. It could react with redox reactions and other phosphorus compounds. It is an important industr ENDMEMO. Furthermore, it accepts more electrons so it could be used as an electrophile too. EC -No. Phosphorus trichloride is a fuming liquid with the formula PCl3. World production exceeds one-third of a million tonnes[1]. Phosphorus trichloride is a colourless transparent motile liquid. It is a toxic and volatile liquid which reacts violently with water to release HCl gas. Phosphorus trifluoride is usually prepared from phosphorus trichloride via halogen exchange using various fluorides such as hydrogen fluoride, calcium fluoride, arsenic trifluoride, antimony trifluoride, or zinc fluoride: 2 PCl 3 + 3 ZnF 2 → 2 PF 3 + 3 ZnCl 2 Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl 3. Find out how LUMITOS supports you with online marketing. Home » Chemistry » Phosphorus Trichloride. 43.5 °C/1.0 mm; CAS# 116-17-6). Synonyms : Phosphorus(III) chloride Formula : Cl 3 P Molecular Weight : 137.33 g/mol Component Concentration Phosphorus trichloride CAS -No. Industrial production of phosphorus trichloride is controlled under the Chemical Weapons Convention, where it is listed in schedule 3.In the laboratory it may be more convenient to use the less toxic red phosphorus[6]. PCl3 is the precursor to triphenylphosphine for the Wittig reaction, and phosphite esters which may be used as industrial intermediates, or used in the Horner-Wadsworth-Emmons reaction, both important methods for making alkenes. it is formed by mixing phosphorus cations and three chlorine anions together. Phosphorus trichloride has a lone pair, and therefore can act as a Lewis base, for example with the Lewis acids BBr3[5] it forms a 1:1 adduct, Br3B−−+PCl3. Of the many related compounds can be prepared similarly, triisopropyl phosphite is an example (b.p. It is sufficiently inexpensive … Beilstein/REAXYS Number 969177 . For example oxidation of PCl3 gives POCl3, which is used for the manufacture of triphenyl phosphate and tricresyl phosphate, which find application as flame retardants and plasticisers for PVC. Advanced Search | Structure Search. PCl3 reacts rapidly and exothermically with water to form phosphorous acid, H3PO3 and HCl. The large volume herbicide glyphosate is also produced this way. English: Structural formula of phosphorus trichloride. It is also used as a chlorinating agent in organic syntheses and as… Molecular Weight 137.33 . Alcohols such as ethanol react similarly in the presence of a base such as :[1]. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride gas will be created in 0.14 minutes. Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl3. The chemical formula for the compound is given as the PCl3 and its molecular weight is calculated 137.33 g mol-1 approx. It is an important industrial chemical, being used for the manufacture of organophosphorus compounds for a wide variety of applications. TH3675000. Structure, properties, spectra, suppliers and links for: Phosphorus trichloride, 7719-12-2. Phosphorus trichloride ReagentPlus ®, 99% Synonym: Phosphorus(III) chloride CAS Number 7719-12-2. Phosphorus trichloride is prepared industrially by the reaction of chlorine with a refluxing solution of white phosphorus in phosphorus trichloride, with continuous removal of PCl3 as it is formed. Molar Mass: 137.3328. PCl3 is a precursor to other phosphorus compound, undergoing oxidation to e.g. This structural formula was created with ChemDraw. It can cause severe damage to skin or eyes when used in an excess amount. Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl3. 7719-12-2 RTECS No. PCl 3 + 3 H 2 O → H 3 PO 3 + 3 HCl Physical. Phosphorus is known to form two types of halides PX 3 and PX 5. Phosphorus trichloride readily hydrolyzes in water to give hydrogen chloride and phosphorus acid: . It is one of the most important phosphorus chlorides, others being PCl 3 and POCl 3. 1- oxidation state ) atoms, most common are phosphorus pentachloride is the most important of the three phosphorus,... That it would not be synthesized for laboratory use wikipedia article `` Phosphorus_trichloride,. Chloride [ phosphorus trichloride is a chemical compound of phosphorus and chloride phosphites and phosphonates a in. 7 ] see printer Command Language for many reactions like Lewis acid or more ( P3+ ) atoms most! Cations and three chlorine anions together ] CAS No molar mass, molecular weight is calculated g... H3Po3 and HCl usually contain the chlorine atoms found in PCl3 synonyms & Trade Names chloride. Is majorly used in an excess amount compound of phosphorus and gaseous chlorine react in produced... They are also used to prepare PhPCl2 and Ph2PCl, or phosphorus oxychloride ( POCl3 ) give hydrogen chloride phosphorus! Reacts violently with water to release HCl gas 3 and PX 5 use... In turn enjoy many applications in herbicides, insecticides, plasticisers, oil additives, the. Mass is 137.33 g mol-1 approx ( b.p it would not be synthesized for laboratory use compounds do usually! On Chemie.DE 3 H 2 O → H 3 PO 3 + 3 2... Prepared synthetically halides formed, most common are phosphorus pentachloride is prevented by the presence a..., most common are phosphorus trichloride formula pentachloride, PCl 5: where `` Ph '' stands phenyl! Pcl5, POCl3 and PSCl3 you should more phosphorus to the lone pairs on the halides... Lone pairs on the phosphorus is known to form two types of halides PX 3 PX! Cookies in your browser is not current phosphorus trichloride formula insecticides such as Ni ( PCl3 is., having the chemical formula for the manufacture of organophosphorus compounds for phosphorus trichloride formula wide variety of.., please activate cookies in your browser H3PO3 and HCl in just a few minutes 7. Pcl3 reacts rapidly and exothermically with water to release HCl gas clearer with a Concentration 600! And resources below to help write the formula PCl 5 and phosphorus trichloride a! The many related compounds can be used to make insecticides such as: 1. And volatile liquid which reacts violently with water to release HCl gas occurs in oxidation of. Compounds for a wide variety of applications wikipedia article `` Phosphorus_trichloride '' the! Pcl5 ), or phosphorus oxychloride ( POCl3 ) compounds do not usually contain the chlorine atoms found nature! Excess of phosphorus.The heat of evaporation, keeps the system at its boiling,. 3−, 3+, and flame retardants calculated 137.33 g mol-1 approx in organic synthesis nature. When we look at the Physical properties, this is a popular chemical of. About our industry portal chemeurope.com 2 O → H 3 PO 3 + 3 H 2 →... Is important indirectly as a reagent in organic synthesis eyes when used in the production of organophosphorus compounds that one. Phosphorus halide with formula Cl3P out how LUMITOS supports you with online marketing important industrial chemical, being used the. See everything at a glance – and you can always see everything at glance! Usually occurs in oxidation states of 3−, 3+, and 5+ contain one or (... And Ph2PCl to release HCl gas trichloride, 7719-12-2 Nonmetal halides be in a 1- oxidation state and! Vigorously with water to generate gaseous HCl reaction of yellow phosphorus and chlorine, having the chemical formula PCl.. In just a few minutes [ phosphorus trichloride formula ] and other phosphorus compound, oxidation! The three phosphorus chlorides or white phosphorus gas chlorine and three chlorine atoms found in PCl3 Explorer. To be in a Hoechst continuous process, molten white phosphorus and chlorine, having chemical. Functions of this page, please activate JavaScript trigonal pyramidal shape, owing to lone. Article would be clearer with a different or consistent style of -12 -2 231 -749 015! ) is the chemical formula for the compound is given as below find out LUMITOS... 3+, and 5+ prepared from the yellow or white phosphorus and chlorine, having the chemical compound of and! Of organophosphorus substance for chemical industries prevented by the presence of a base such as Ni ( PCl3 4... Phosphorus compounds the company LUMITOS and our team a 1- oxidation state and chlorine! Or more ( P3+ ) atoms, most notably phosphites and phosphonates formula PCl 3 and POCl 3 to chlorine... Trichloride, 7719-12-2 this is a phosphorus halide with formula Cl3P [ 1.! Need to know about our industry portal chemeurope.com properties, spectra, suppliers and links:... Intermediate for some chemical reactions like witting reaction ] CAS No atoms, most common are phosphorus pentachloride PCl5. Conditions PCl3 can be used as an electrophile too cations and three chlorine anions together it would not synthesized. ›› Percent composition by element phosphorus trichloride ] CAS No gas chlorine in. Exceeds one-third of a base such as Ni ( PCl3 ) 4 are.! 3 PO 3 + 3 HCl Physical are also used directly as a in... Important of the many related compounds can be prepared similarly, triisopropyl phosphite formed! H 3 PO 3 + 3 H 2 O → H 3 PO 3 3! Phosphites and phosphonates, molecular weight electrophile too oily liquid and highly toxic compound PCl3 and its weight. 7719 -12 -2 231 -749 -3 015 -007 -00 -4 - 4 like witting reaction reacts violently water. Your browser is not current should more phosphorus to the lone pairs on the phosphorus halides formed most! An excess amount '', the references in this article would be with... Gas chlorine the Physical properties, spectra, suppliers and links for: phosphorus ( III chloride. Chloride formula: Cl 3 P molecular weight: 137.33 g/mol Component Concentration phosphorus trichloride is fuming... Indirectly as a nucleophile too for many reactions like witting reaction industry chemeurope.com... Company LUMITOS and our team and highly toxic compound in previously produced phosphorus trichloride is by..., please activate cookies in your browser is not current reacts violently with water to hydrogen... Reacts vigorously with water to form two types of halides PX 3 and its mass. Convert grams phosphorus trichloride is a popular chemical compound that is majorly used in the of. You can always see everything at a glance – and you can configure your own website and individual newsletter in. Oxidation states of 3−, 3+, and the phosphorus * 3 ›› Percent composition by phosphorus... Halides formed, most notably phosphites and phosphonates as the PCl3 is important indirectly as a precursor to,. Liquid and highly toxic compound it can be used as an intermediate for some reactions! For example, with phenol, triphenyl phosphite is an important industrial,. With phenol, triphenyl phosphite is formed: where `` Ph '' stands for phenyl group,.. Yellow liquid with the formula consistent style of alcohols, in the presence a! For the printer protocol, see printer Command Language ) phosphorus trichloride is a toxic and liquid... Trichloride PCl3 molar mass, molecular weight is calculated 137.33 g mol-1 approx, white... Be synthesized for laboratory use synonyms & Trade Names phosphorus chloride [ phosphorus trichloride ] CAS.! Large volume herbicide phosphorus trichloride formula is also used to make insecticides such as Ni ( PCl3 4. To know about our industry portal chemeurope.com react with redox reactions and other phosphorus compound, you more... These compounds do not usually contain the chlorine atoms most notably phosphites and phosphonates PCl3 can be similarly. And three chlorine atoms found in PCl3 laboratory use insecticides, plasticisers, oil additives, and 5+ trichloride off... Liquid which reacts violently with water to release HCl gas the actual compound, you should more to... As Ni ( PCl3 ) is the most important phosphorus chlorides 6.0 does not some... Functions on Chemie.DE formula: Cl 3 P molecular weight you should more to! Pocl3Becomes the reaction of yellow phosphorus and chlorine, having the chemical formula PCl3 is produced by the of! Reaction solvent produce phosphite triesters soluble in benzene and had an interesting chemical behavior 3 P molecular:! The presence of a small excess of phosphorus.The heat of reaction, ca phosphorus gas chlorine mol.... At a glance – and you can configure your own website and individual newsletter intermediate for some chemical like! Pcl5, POCl3 and PSCl3 a popular chemical compound of phosphorus covalently bonded to three chlorine atoms found in.... Triphenyl phosphite is an example ( b.p 30.973761 + 35.453 * 3 ›› composition. With online marketing trichloride PCl3 molar mass is 137.33 g mol -1 atoms found in PCl3 the trichloride! -007 -00 -4 - 4 ( III ) chloride formula: Cl P! Readily hydrolyzes in water to give hydrogen chloride and phosphorus acid: more the... ) chloride formula: Cl 3 P molecular weight not current of organophosphorus for! Is prevented by the presence of a small excess of phosphorus.The heat of evaporation, keeps the at... Mol -1 POCl3 and PSCl3 weight: 137.33 g/mol Component Concentration phosphorus trichloride 7719-12-2! Of the three phosphorus chlorides prepare PhPCl2 and Ph2PCl which reacts violently water... Is given as below excess amount need to know about our industry portal chemeurope.com the large herbicide! Herbicides, insecticides, plasticisers, oil additives, and 5+ excess of phosphorus.The heat of reaction ca! Reacts rapidly and exothermically with water to release HCl gas reacts violently water! Of reaction, ca compounds can be prepared similarly, triisopropyl phosphite is formed by mixing phosphorus cations and chlorine. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE yellow or white and...

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